Before you proceed make sure that you run apt-get update from terminal. Check the necessary repository in sources.list file. For more please read this
post.
STEPS:
1. Goto
www.skype.com and click on
Downloads.
2. Being a Kali Linux user, select
Choose your distribution as
debian and click
Save File to download.

3. Open terminal and locate the downloaded file.
4. Run
dkpg -i skype-debian_x.x.x.x_i386.deb (where x is the version of skype) to install the package.

5. Type skype to run the program.
6. Accept License agreement.